Lianzhou Refrigerants
R-410A
Material Safety Data Sheet Information
1.CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: R-410A
DISTRIBUTOR: h ejiang Quzhou Lianzhou Refrigerants Co., Ltd.
FOR MORE INFORMATION CALL:
86-570-3617486
2.COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT NAME CAS NUMBER WEIGHT % Difluoromethane        75-10-5        50 Pentafluoroethane      354-33-6        50
Trace impurities and additional material names not listed above may also appear in Section 15 toward the end of the MSDS.  These materials may be listed for local “Right-To-Know” compliance and for other reasons.
reactive materials studies
3.HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:  Colorless, volatile liquid with ethereal and faint sweetish odor.  Non-flammable material.
Overexposure may cause dizziness and loss of concentration.  At higher levels, CNS depression and cardiac arrhythmia may result from exposure.  Vapors displace air and can cause asphyxiation in confined spaces.  At higher temperatures, (>250°C), decomposition products may include Hydrofluoric Acid (HF) and carbonyl halides.
POTENTIAL HEALTH HAZARDS
SKIN:Irritation would result from a defatting action on tissue.  Liquid contact could cause frostbite.
EYES: Liquid contact can cause severe irritation and frostbite.  Mist may irritate.
INHALATION: R-410A is low in acute toxicity in animals.  When oxygen levels in air are reduced to 12-14% by
displacement, symptoms of asphyxiation, loss of coordination, increased pulse rate and deeper respiration
will occur.  At high levels, cardiac arrhythmia may occur.
Lianzhou Refrigerants
R-410A INGESTION:  Ingestion is unlikely because of the low boiling point of the material.  Should it occur, discomfort in the            gastrointestinal tract from rapid evaporation of the material and consequent evolution of gas would result.
Some effects of inhalation and skin exposure would be expected.
DELAYED EFFECTS:  None known.
Ingredients found on one of the OSHA designated carcinogen lists are listed below.
INGREDIENT NAME NTP STATUS IARC STATUS OSHA LIST
No ingredients listed in this section
4.FIRST AID MEASURES
SKIN:Promptly flush skin with water until all chemical is removed.  If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water.  If water is not available, cover with a clean, soft cloth or similar covering.  Get medical attention if symptoms persist.
EYES:Immediately flush eyes with large amounts of water for at least 15 minutes (in case of  frostbite water should be lukewarm, not hot) lifting eyelids occasionally to facilitate irrigation.  Get medical attention if symptoms persist.
INHALATION: Immediately remove to fresh air.  If breathing has stopped, give artificial respiration.  Use oxygen as required,  provided a qualified operator is available.  Get medical attention.  Do not give epinephrine (adrenaline).
INGESTION:Ingestion is unlikely because of the physical properties and is not expected to be hazardous.  Do not induce vomiting unless instructed to do so by a physician.
ADVICE TO PHYSICIAN: Because of the possible disturbances of cardiac rhythm, catecholamine drug
s, such as
used with special caution and only in situations of emergency life support.
should
be
epinephrine,
directed
at the control of symptoms and the clinical
be
overexposure
should
of
Treatment
conditions.
5.FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
regulations
DOT
FLASH POINT:    Gas,
not
applicable
per
FLASH POINT METHOD:Not
applicable
AUTOIGNITION TEMPERATURE: >750°C
UPPER FLAME LIMIT (volume % in air):None by ASTM D-56-82
LOWER FLAME LIMIT (volume % in air):None by ASTM E-681
applicable
FLAME PROPAGATION RATE (solids): Not
OSHA FLAMMABILITY CLASS:  Not
applicable
EXTINGUISHING MEDIA:
Use any standard agent – choose the one most appropriate for type of surrounding fire (material itself is not flammable)
R-410A
UNUSUAL FIRE AND EXPLOSION HAZARDS:
R-410A is not flammable at ambient temperatures and atmospheric pressure.  However, this material will become
combustible when mixed with air under pressure and exposed to strong ignition sources.
Contact with certain reactive metals may result in formation of explosive or exothermic reactions under specific conditions
(e.g. very high temperatures and/or appropriate pressures).
SPECIAL FIRE FIGHTING PRECAUTIONS/INSTRUCTIONS:
Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against possible toxic
decomposition products.  Proper eye and skin protection should be provided.  Use water spray to keep fire-exposed cool.
containers
6.ACCIDENTAL RELEASE MEASURES
IN CASE OF SPILL OR OTHER RELEASE:(Always wear recommended personal protective equipment.) Evacuate unprotected personnel.  Protected personnel should remove ignition sources and shut off leak, if without risk, and provide ventilation.  Unprotected personnel should not return until air has been tested and determined safe, including low-areas.
lying
Spills and releases may have to be reported to Federal and/or local authorities.  See Section 15 regarding reporting requirements.
7.HANDLING AND STORAGE
personal protective equipment.)
recommended
NORMAL HANDLING:    (Always
wear
Avoid breathing vapors and liquid contact with eyes, skin or clothing.  Do not puncture or drop cylinders, expose them to
open flame or excessive heat.  Use authorized cylinders only.  Follow standard safety precautions for handling and use of
compressed gas cylinders.
R-410A should not be mixed with air above atmospheric pressure for leak testing or any other purpose.
STORAGE RECOMMENDATIONS:
Store in a cool, well-ventilated area of low fire risk and out of direct sunlight.  Protect cylinder and its fittings from physical damage.  Storage in subsurface locations should be avoided.  Close valve tightly after use and when empty.
8.EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS:
Provide local ventilation at filling zones and areas where leakage is probable.  Mechanical (general) ventilation may be
adequate for other operating and storage areas.
PERSONAL PROTECTIVE EQUIPMENT
SKIN PROTECTION:
Skin contact with refrigerant may cause frostbite.  General work clothing and gloves (leather) should provide
adequate protection.  If prolonged contact with the liquid or gas is anticipated, insulated gloves constructed of PVA,
neoprene or butyl rubber should be used.  Any contaminated clothing should be promptly removed and washed  reuse.
before
R-410A EYE PROTECTION:
For normal conditions, wear safety glasses.  Where there is reasonable probability of liquid contact, wear chemical safety
goggles.
RESPIRATORY PROTECTION:
None generally required for adequately ventilated work situations.  For accidental release or non-ventilated situations, or
release into confined space, where the concentration may be above the PEL of 1,000 ppm, use a self-contained, NIOSH-
approved breathing apparatus or supplied air respirator.  For escape:  use the former or a NIOSH-approved gas mask with vapor
canister.
organic
ADDITIONAL RECOMMENDATIONS:
Where contact with liquid is likely, such as in a spill or leak, impervious boots and clothing should be worn.  High dose-level warning signs are recommended for areas of principle exposure.  Provide eyewash stations and quick-drench shower facilities at convenient locations.  For tank cleaning operations, see OSHA regulations, 29 CFR 1910.132 and 29 CFR 1910.133.
EXPOSURE GUIDELINES
INGREDIENT NAME ACGIH TLV OSHA PEL OTHER LIMIT
Difluoromethane      None        None          None
Pentafluoroethane      None      None  *1000 ppm TWA (8hr)
*    =  Workplace Environmental Exposure Level (AIHA)
OTHER EXPOSURE LIMITS FOR POTENTIAL DECOMPOSITION PRODUCTS:
Hydrogen Fluoride:  ACGIH TLV:  3 ppm ceiling
9.PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE:Clear, colorless liquid and vapor
PHYSICAL STATE:Gas at ambient temperatures
MOLECULAR WEIGHT:  72.6
CHEMICAL FORMULA:  CH2F2, CHF2CF3
ODOR:    Faint
odor
ethereal
SPECIFIC GRAVITY (water = 1.0):  1.08 @ 21.1°C (70°F)
SOLUBILITY IN WATER (weight %): Unknown
pH: Neutral
BOILING POINT:-48.5°C (-55.4°F)
determined
FREEZING POINT:  Not
VAPOR PRESSURE:215.3 psia @ 70°F
490.2 psia @ 130°F
VAPOR DENSITY (air = 1.0):  3.0
EVAPORATION RATE:  >1 COMPARED TO:  CC14  =  1
% VOLATILES:  100
applicable
FLASH POINT:  Not
(Flash point method and additional flammability data are found in Section 5.)
Lianzhou Refrigerants
R-410A 10.STABILITY AND REACTIVITY
NORMALLY STABLE?  (CONDITIONS TO AVOID):
The product is stable.
Do not mix with oxygen or air above atmospheric pressure.  Any source of high temperature, such as lighted cigarettes,
flames, hot spots or welding may yield toxic and/or corrosive decomposition products.
INCOMPATIBILITIES:
(Under specific conditions:  e.g. very high temperatures and/or appropriate pressures) – Freshly abraded aluminum surfaces (may cause strong exothermic reaction).  Chemically active metals:  potassium, calcium, powdered aluminum, magnesium zinc.
and
HAZARDOUS DECOMPOSITION PRODUCTS:
Halogens, halogen acids and possibly carbonyl halides.
HAZARDOUS POLYMERIZATION:
Will not occur.
11.TOXICOLOGICAL INFORMATION
IMMEDIATE (ACUTE) EFFECTS:
Difluoromethane: LC50 : 4 hr. (rat) - > 520,000 ppm
Pentafluoroethane: Cardiac Sensitization threshold (dog) > 100,000 ppm
DELAYED (SUBCHRONIC AND CHRONIC) EFFECTS:
Teratology – negative
Subchronic inhalation (rat) NOEL – 50,000 ppm
OTHER DATA:
Not active in four genetic studies
12.ECOLOGICAL INFORMATION
Degradability (BOD):      R-410A is a gas at room temperature; therefore, it is unlikely to remain in water.
Octanol Water Partition Coefficient:  Log P ow = 1.48 (pentafluoroethane), 0.21 (difluoromethane)

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