“S olving customers formulating challenges with novel performance additives.”
Ether Nitriles
Ether Amines
Alcohols:
Linear and Branched
to C 20
Air Products is the world’s largest producer of ether amines and ether amine derivatives with an expertise in cationic and amphoteric surfactants. This market leading position starts from a strong commitment to invest in technology, research and people…and is further developed through our strong relationships with customers.
At the core of these strong relationships is our deeper understanding of our customer’s needs and challenges. Our experienced technical team works hand-to-hand with customers to develop effective solutions. Whether it’s an environmental benefit, improving the performance of an existing product, or ma
king a production process more cost effective, customers are always looking for assistance and ways to do things better than others in their market. We have been providing that edge for over 40 years. Select product applications:
• Hard surface cleaning • Detergent boosters • Foaming agents • Viscosity builders
• Mineral flotation collectors
• Liquid alternatives to solid fatty amines • Lubrication additives • Fuel additives
• Agricultural additives • Antistatic agents • Corrosion inhibitors
• Cross linking agents for epoxy resins Formulating can be a complex process. This product guide offers a good starting point providing an overview of our ether amine and ether amine derivative products. For free samples or technical assistance please call us at 800-345-3148. You can also visit our web site at www.airproducts/nimble .
Amine Oxides (AO-Series)
(CH2CH2O)x H
R-O-CH2CH2CH2 N O
(CH2CH2O)n-x H
These products are excellent foam boosters and stabilizers. They are also excellent detergents. Amine oxides tend to act non-ionically in neutral and alkaline pH. Tomamine AO-14-250% active bis-(2-hydroxyethyl) isodecyloxypropylamine
oxide
Tomamine AO-72850% active linear alkyloxypropylamine oxide Tomamine AO-40550% active low-foam alkyloxypropylamine oxide Tomamine AO-45550% active low-foam alkyloxypropylamine oxide
Amphoteric Surfactants
Air Products amphoteric surfactants are designed for use in alkaline and acidic cleaners. They offer exceptional coupling stability and wetting in a wide range of formulations that may contain other anionic, nonionic, and cationic surfactants. Scrub tests indicate improved detergency in formulations containing Tomamine Amphoteric surfactants.
O
CH2CH2C — O v Na B
R-O-CH2CH2CH2N
CH2CH2C — OH
O
Listed in increasing order of coupling ability.
Tomamine Amphoteric L37% active; high foaming hydrotrope Tomamine Amphoteric SC35% active; high foaming hydrotrope Tomamine Amphoteric 1633% active biodegradable; high foaming,
hydrotroping surfactant
Tomamine Amphoteric LH30% active; moderate foaming hydrotrope Tomamine Alkali Surfactant35% active; moderate foaming hydrotrope Tomamine Amphoteric 40050% active; low foaming hydrotrope Tomamine Amphoteric 1235% active biodegradable; low foaming,
hydrotroping surfactant Spraywax Emulsifiers & Drying Agents Tomamine Emulsifier Four75% active dialkyl quaternary designed for
emulsification of non-polar hydrophobes,
particularly mineral seal oil.
Tomamine Emulsifier Four HF A modified high-flash version of Emulsifier
Four. The flash point is above 200 °F Tomadry TM N-4 Drying Agent100% active super-concentrated mineral
seal oil-containing drying agent. Made with
Emulsifier Four.
Tomadry N-3 Drying Agent100% active non oil-containing super-
concentrated drying agent. Contains ethylene
glycol monobutyl ether.
Tomadry N-5C Drying Agent100% active non oil-containing drying agent.
Designed for quick water break and water
beading.
Tomadry N-7 Drying Agent100% active non oil-containing super-
concentrated drying agent. Does not contain
ethylene glycol monobutyl ether. Tomadry N-8 Drying Agent A high-flash version of Tomadry N-4. Made
with Emulsifier Four HF.
Tomamine Emulsion C-340A 18% active cationic emulsion of carnauba
wax. Used for “hot carnauba” drying agents. Tomadry DAB Drying Additive A 100% active wax additive designed
for formulation into a wide variety of
transportation cleaning applications. Tomamine Emulsifier 300A balanced emulsifier for Mineral Seal Oil
(MSO) and other hydrophobes in water
used to optimize drying efficiency for vehicle
care products.
Tomamine Emulsifier 300HF A high-flash version of Tomamine
Emulsifier 300.
Acid Additives & Acid Inhibitors
Tomamine Acid Foamer100% active foaming additive for organic and
inorganic acids.
Tomamine Acid Thickener100% active thickener for organic and inorganic
acids.
Tomamine Inhibitor 60S A cid inhibitor for hydrochloric acid and other acids. Tomamine Inhibitor 60Q Acid inhibitor for many mineral acids.
Asphalt & Coal Tar Sealant Additives
• T omamine PA-14 Acetate is a patented 100% active cationic surfactant designed to wet various clays, fillers, and fibers resulting in a stable and desirable end-use viscosity for asphalt coatings and sealants.
Tomamine® Ether Amines
Tomamine aliphatic ether amines are a unique class of industrial chemicals with broad range properties. Tomamine PA- and DA- series synthetic ether amines are produced by the reaction of an aliphatic alcohol with acrylonitrile. These unique primary ether amines can be used as additives or building blocks for many other surfactants with broad applications.
R-OH + CH2CHCN R-O-CH2CH2CN + 2 H2
Alcohol Acrylonitrile Ether Nitrile Hydrogen
R-O-CH2CH2CH2NH2 + Acrylonitrile + Hydrogen R-O-(CH2)3NH(CH2)3NH2 Ether Amine (PA-Series) Ether Diamine (DA-Series)
Ether Amines (PA-Series)
Tomamine PA-10L Hexyloxypropyl amine
Tomamine PA-12EH2-Ethylhexyloxypropyl amine
Tomamine PA-1214Octyl/decyloxypropyl amine
Tomamine PA-14Isodecyloxypropyl amine
Tomamine PA-1618Dodecyl/tetradecyloxypropyl amine Tomamine PA-17Isotridecyloxypropyl amine
Tomamine PA-1816Tetradecyl/dodecyloxypropyl amine Tomamine PA-19Linear alkyloxypropyl amine
Ether Diamines (DA-Series)
Tomamine DA-1214 Octyl/decyloxypropyl-1,3-diaminopropane Tomamine DA-14 Isodecyloxypropyl-1,3-diaminopropane Tomamine DA-1618Dodecyl/tetradecyloxypropyl-1,3-diaminopropane Tomamine DA-17 Isotridecyloxypropyl-1,3-diaminopropane Ethoxylated Amines (E-Series)
Air Products produces a wide range of ethoxylated ether amines and ethoxylated fatty amines. These amines have been reacted with various amounts of ethylene oxide to modify emulsification, surface tension, solubility and cationic strength. Some of the more popular uses of the E-Series products are: acid thickening, detergent boosting and textile processing aids.
(CH2CH2O)x H
R-O-CH2CH2CH2N
(CH2CH2O)n-x H
Tomamine E-14-2bis-(2-hydroxyethyl) isodecyloxypropylamine Tomamine E-14-5poly (5) oxyethylene isodecyloxypropylamine Tomamine E-17-2bis-(2-hydroxyethyl) isotridecyloxypropylamine Tomamine E-17-5poly (5) oxyethylene isotridecyloxypropylamine Tomamine E-T-2b is-(2-hydroxyethyl) tallow amine
(and 5 & 15-mole adducts)
Tomamine E-DT-3N-tallow-poly (3) oxyethylene-1,3-diaminopropane
Quaternary Amines (Q-Series)
Air Products quaternary amines are based on the reaction of aliphatic tertiary amines with methyl chloride using isopropanol or glycols as a diluent.
(CH2CH2O)x H
R-O-CH2CH2CH2N B (CH2CH2O)n-x H Cl v
CH3
Tomamine Q-14-275% active isodecyloxypropyl bis-(2-hydroxyethyl)
methyl ammonium chloride
(Available in propylene glycol)
Tomamine Q-17-275% active isotridecyloxypropyl bis-(2-hydroxyethyl)
methyl ammonium chloride
(Available in propylene glycol)
Tomamine Q-S-70HG70% active mono soya methyl ammonium chloride Tomamine Q-DT-HG50% active tallow diamine diquaternary Tomamine Q-C-15100% active coco poly (15) oxyethylene methyl
ammonium chloride
The Tomamine DA-series synthetic ether diamines are produced by the reaction of an aliphatic alcohol with two moles of acrylonitrile. Like the Tomamine PA-series, these unique ether diamines can be used as additives or building blocks for many other surfactants
with broad applications use. The Tomamine DA-series ether diamines have excellent low temperature liquidity.
Product R Equals Description
Tomamine DA-1214 C 8H 17/C 10H 21O ctyl/decyloxypropyl-1,3-diaminopropane Tomamine DA-14 Branched C 10H 21 I sodecyloxypropyl-1,3-diaminopropane Tomamine DA-1618 C 12H 25/C 14H 29 D odecyl/tetradecyloxypropyl-1, 3-diaminopropane Tomamine DA-17
Branched C 13H 27 I sotridecyloxypropyl-1,3-diaminopropane
Tomamine DA-Series Ether Amines
TYPICAL PROPERTIES DA-1214 DA-14 DA-1618 DA-17Molecular Wt.
290 295 340 330Min. amine value 385 375 330 325Min. mole% primary amine 49 49 49 49Water cont
ent, %max 0.5 0.5 0.5 0.5Flash point, °F >200 >200 >200 >200SpG 25 °C 0.87 0.87 0.87 0.87Gardner color, max 5 5 5 5Pour point, °F 20 -50 60 -30Physical form @ 25 °C
liquid
liquid
paste
liquid
H
R-O-CH 2CH 2CH 2N
CH 2CH 2CH 2NH 2
Product R Equals Description Tomamine PA-10L C 6H 13 Hexyloxypropyl amine Tomamine PA-12EH Branched C 8H 172-Ethylhexyloxypropyl amine
Tomamine PA-1214 C 8H 17/C 10H 21O ctyl/decyloxypropyl amine
Tomamine PA-14 Branched C 10H 21I sodecyloxypropyl amine Tomamine PA-1618
C 12H 25/C 14H 29
D
odecyl/ tetradecyloxypropyl amine
Product R Equals Description Tomamine PA-17 Branched C 13H 27I sotridecyloxypropyl amine
Tomamine PA-1816 C 14H 29/C 12H 25T
etradecyl/ dodecyloxypropyl amine Tomamine PA-19
C 12H 25/C 15H 31
L inear alkyloxypropyl amine
The Tomamine PA-series synthetic ether amines are produced by the reaction of an aliphatic alcohol with acrylonitrile. These unique primary ether amines can be used as additives or building blocks for many other surfactants with broad applications. Ether amines have excellent
low temperature liquidity. Some of the more popular uses for the Tomamine PA-series products include:
corrosion inhibitors, lubrication additives, fuel additives, and mineral flotation collectors.
Tomamine PA-Series Ether Amines
react withTYPICAL PROPERTIES PA-10L PA-12EH PA-1214 PA-14 PA-1618 PA-17 PA-1816 PA-19Molecular Wt. 165 200 207 225 260 265 265 272Min. amine value 315 280 260 243 200 200 200 195Min. mole% primary amine 96
96
96
96
96
96
96
96
Water content, %max 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5Flash point, °F 183 >200 >200 >200 >200 >200 >200 >200SpG 25 °C
0.84
0.85
0.85
0.85
0.85
0.85
0.85
0.85
Gardner color, max 5 5 5 5 5 5 5 5Pour point, °F -30 -30 20 -50 50 -30 50 50Physical form @ 25 °C
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Paste
Paste
R-O-CH 2CH 2CH 2NH 2
Tomamine E-series Ethoxylated Amines
The Tomamine E-Series amines have a broad range of applications. Some of the suggested uses include:• D egreasers
• A nti-static agents • T extile processing aids • C ationic emulsification • D etergent boosters
• I ntermediates for the manufacture of quaternaries
and amine oxides
Suggested Formulations
Premium Laundry Detergent Component
Weight %
Water 79.0Tomamine E-14-2 Surfactant 3.0Tomadol ® 91-8 Surfactant 7.0Tomamine Alkali Surfactant 5.0Tetrapotassium pyrophosphate 4.0Sodium metasilicate pentahydrate
2.0
Total 100.0
Ternary General Purpose Cleaner/Detergent
Component Weight %Tomamine E-14-2 Surfactant 25.0Tomamine Q-17-2 PG Surfactant 25.0Tomadol 91-6 Surfactant
50.0
Total 100.0
Dilute 1 part of this blend with 99 parts of water. Lab studies have shown that the ternary blend is extremely effective without builders at high dilutions for degreasing hydrophobic paraffin-containing non-polar soils.
Terpene Microemulsion Degreaser
Component Weight %Dipentene 122
5.0Tomamine E-14-5 Surfactant
6.4Tomamine E-14-2 Surfactant 0.8Tomamine Alkali Surfactant
0.8
Water 87.0Total 100.0
Air Products produces a wide range of ethoxylated ether amines and ethoxylated fatty amines. These amines have been reacted with various amounts of ethylene oxide to modify emulsification, surface tension, solubility and cationic strength. Some of the more popular uses
of the Tomamine E-Series products include: acid thickening, microemulsification, detergent boosting, and textile processing aids. The Tomamine E-Series ether amines are represented by the formula above, where R is the alkyl radical and n is the total number of moles of ethylene oxide.
Product R Equals Description
Tomamine E-14-2 Branched C 10H 21b is-(2-hydroxyethyl) isodecyloxypropylamine Tomamine E-14-5 Branched C 10H 21
p oly (5) oxyethylene isodecyloxypropylamine Tomamine E-17-2 Branched C 13H 27b is-(2-hydroxyethyl) isotridecyloxypropylamine Tomamine E-17-5 Branched C 13H 27
p oly (5) oxyethylene isotridecyloxypropylamine Tomamine E-T-2
Stearic/Oleic
b is-(2-hydroxyethyl) tallow amine (CH 2CH 2O)x H R-O-CH 2CH 2CH 2N
(CH 2CH 2O)n-x H
Tomamine Ethoxylated Amines
TYPICAL PROPERTIES E-14-2 E-14-5 E-17-2 E-17-5 E-T-2Molecular Wt. 310 445 345 485 360Min. amine value
175
123
155
112
156
% tertiary amine 97 100 97 100 97Flash point, °F >200 >200 >200 >200 >200SpG 25°C 0.94 0.99 0.94 0.99 0.91Gardner color, max 9 11 9 11 16Pour point, °F 20 20 20 20 50Physical form @ 25°C
Liquid
Liquid
Liquid
Liquid
Paste
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