Advanced Organic Chemistry
Yan Zhang g
njuzy@nju.edu
Tel:
83593072
Overview
•Objective:deeper understanding on structure and mechanism & their relationship
general    data  •Contents:principles&specific and examples to illustrate them
•Application:structureÆreactivityÆsynthesis and transformations
Books
Reference  1Modern Physical Organic Chemistry (2004E V Anslyn D A Doupherty)1.    (2004, E.V. Anslyn, D. A.Doupherty) ‐‐‐translated  version  (【译者】计国桢；佟振合[同译者作品]
【出版社】高等教育出版社
【书号】9787040263596)2.
Advanced  Organic  Chemistry  (F. A. Carey, R. J. Sundburg)3.
The  Art  of  Writing  Reasonable  Organic  Reaction  Mechanisms  (2nd  Ed. Robert  B, Grossman)4.Advanced  Organic  Chemistry  (M.B. Smith, J. March) ‐‐‐translated  version  (March  高等有机化学‐‐‐反应，机理与结构李艳梅译化学工业出版社)
Contents •Molecular Structure and Thermodynamics 1.Structure and models of bonding
2and Stability
2.Strain
3.Non‐covalent binding forces
reaction kinetics mechanism期刊4.Acid‐Base Chemistry
5.Stereochemistry y
•Reactivity & Kinetics
6.Kinetic Analyses
6Ki ti A l
7.Experiments related to thermodynamics and kinetics
8.Catalysis
•Reactions & Synthesis
Chapter 1 Structure and models of bonding
p
1.1 Classical valence bond concepts:
,g
•atomic orbitals, electron configurations
•hybridization, σand πbonds
•inductive effects, electronegativity, bond dipoles, molecular dipole moments •resonance
•polarizability
Electronegativity of atoms and groups Table 1.1

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