28辽宁化工2021年1月
尽管如此，MOFs所具备的结构灵活和成分可调等固有优点，对其在储能和转换之外的潜在性能和应用的探索将是一个持久的发展方向。而随着对其复杂反应过程背后的基础科学的不断研究，表征和合成技术的快速发展，MOFs基衍生物将在催化、气体存储/分离、光电子和药物传递等领域迎来另一个飞跃。
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Metal-organic Frameworks-based Catalyst for Oxygen Evolution Reaction
WANG YuZHANG Shu,LI Zi-yi,YU Zhou
(College of Chemistry and Chemical Engineering,Shenyang Normal University,Shenyang Liaoning110034,China)
Abstract:Oxygen evolution reaction(OER)plays an important role in electrochemical hydrocracking,providing a more feasible way for sustainable hydrogen production.The derivatives derived from metal organic framework(MOFs)have the advantages of controllable structure/composition,high surface area and ordered pore structure.In this paper,the research progress
of MOFs-based derivatives in OER applications in recent years was reviewed.The examples presented can provide some reference for the preparation of highly active MOFs-based derivatives.Finally,the challenges and prospects of the engineering of MOF-based electrocatalysts were prospected.
Key words:Metal organic framework;Oxygen evolution reaction;Non-precious metal catalysts
大连化学物理研究所科研成果介绍
异丁烯高附加值下游产品
甲基丙烯膳和甲基丙烯酸甲酯制备工艺研究
负责人：高爽电话：84379248联络人：王连月Email：************
学科领域：精细化工项目阶段：实验室开发reaction研究
项目简介及应用领域
我国石油化工催化裂解装置副产大量G资源，主要成分为丁二烯、叔丁醇、异丁烯等：经过分离丁二烯
等其他成分后，可得到大啟叔丁醇、异丁烯，而R在催化剂作用下叔丁醇可脱水得到异丁烯，因此以异丁烯为原料制备其高附加值下游产品甲基丙烯睛和甲基丙烯酸甲酯是充分利用C4的有效途径目前，工业上以异丁烯为原料直接制备甲基內烯睛是高温气相反应工艺甲基丙烯酸甲酯的制备匚艺主要是三步法，并且国外垄断现有的主要匸艺技术：由异丁烯催化氧化得到甲基，再由甲基直接氧化氨（或酯化）为甲基丙烯睛（或者甲基内烯酸甲酯）；该工艺路线简化了甲基氧化过程及分离中间产物的设备，原子经济性高，可实现甲基丙烯睛和甲基丙酸甲酯的绿化生产目前.异丁烯制备甲基技术已经成熟，本项目为甲基一步液相催化氧化氨化（或者酯化）为甲基丙烯睛（或者甲基丙烯酸甲酯）甲基丙烯睛：甲基丙烯睛是一种重要的有机合成原料，尤其是制备聚甲基丙烯酰亚胺（PMI）的原料—
—重要的芯层材料.用于航空航天、车辆、船舶等高科技领域研发了一种禽链催化剂材料用于制造型料、涂料、粘合剂、PVC改性剂、高档轿车漆、纺织浆料、髙级酯类油品添加剂等精细化学品研发由一种甲基分钟氧选择氧化同时和甲醇发生酯化反应生成甲基内烯酸甲酯的新型纳米金催化剂材料.与已有T.业化催化材料相比，本项冃催化材料制备过程简单.催化剂成分简单.反应条件温和.催化剂效率高等特点
合作方式：合作开发；投资规模：100万~500万

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