carbohydrates
The food scientist has a many-sided interest in carbohydrates. He is concerned with their amounts in various foods, availability (nutritional and economic), methods of extraction and analysis, commercial forms and purity, nutritional valve, physiological effects, and functional properties in foods. Understanding their functional properties in processed foods requires not only knowledge of the physical and chemical properties of isolated carbohydrates, but also knowledge of the reactions and interactions that occur in situs between carbohydrates and other food constituents and the effects of these changes upon food quality and acceptance. This is a tall order for knowledge. Because processing affects both nutritional and esthetic values of food, knowledge of the changes that carbohydrates undergo during milling, cooking, dehydration, freezing, and storage is especially important.
Students are advised to study the fundamental chemistry underlying useful carbohydrates properties Of service will be an understanding of the association of polar molecules through hydrogen bonding, ionic effects, substituent effects, chelation with inorganic ions, complexing with lipids and proteins, and decomposition reaction. This background will provide an understanding of properties that affect the texture and acceptance of processed foods (e.g., solubility, hygroscopicity, diffusion, osmosis, viscosity, plastity, and flavor production), properties that enable the formation or high quality pastries, gels, coating
s, confections, and reconstitutable dehydrated and frozen foods.
Ability to predict what changes in functional properties are likely to ensue from incorporating various types of carbohydrates into processed foods is a practical goal of the food scientist.Such forecasting requires either a wealth of experience with trial-and-error methods or a deep knowledge of carbohydrate properties as related to structure—perhaps both. However, scientific knowledge of cause and effect is highly respected when it shortens industrial development time
Source, Types, and Terminology
The layman‟s conception of carbohydrates generally involves only the sugars and starches of foods—those that generate calories and fat. The food chemist knows many other types that are ingested.
Because most people enjoy the sweetness of sugars and the mouth feel of cooked starches, they become familiar by association with table sugar (sucrose), invert sugar‟s hydrolyzed sucrose, corn syrup sugars (D-glucose and maltose), milk sugar (lactose), and the more starchy foods. These carbohydrates are nutritionally available; i .e., they are digested (hydrolyzed to component monosaccharides) and utilized by the human body。Carbohydrates of dietary fiber (cellulose, hemicelluse,  pentosans, and pectic substances), in contrast, tend to be overlooked because they are l
argely unavailable. Digestive enzymes do not hydrolyze them significantly; nevertheless, they may be quite important for human health.
The carbohydrates of natural and processed foods are divided into available and unavailable
types. The available carbohydrates vary in degrees of absorption and utilization depending upon quantities ingested, accompanying food types, and human differences in complements of defective enzymes and intestinal transport mechanisms. Malabsorption difficulties and adverse physiological effects are known for all the available carbohydrates but gelatinized starches give little or no trouble.
It is important to realize that in ruminants the unavailable and most abundant polysaccharide cellulose is partially hydrolyzed to the same highly available sugar that starch provides upon digestion; i.e. D-glucose. Grazing animals do it through the celluloses generated by the microorganisms of their rumen. Cellulose is, therefore, a contributing source of voluble animal protein. Food chemists probably can improve upon the efficiency and economics of the ruminant‟s conversion of cellulose to nutrients. Development of celluloses that are stable outside the cells of microorganisms enables the culturing of fungi and with yeasts on cellulose hydrolyzates. Fungi (e.g., mushrooms) can produce protein with the biological value of animal protein. The conversion of cellulose wastes to animal feed and human food i
s an intriguing prospect for limiting environmental pollution and for feeding the world‟ expending population.
Carbohydrates were first named according to their natural sources; e.g., beet sugar, cane sugar, grape sugar, malt sugar, milk sugar, cornstarch, liver glycogen, and sweet corn glycogen. Trivial names were then formed, in English terminology, often from a prefix related to the source followed by the suffix “-ose” to denote carbohydrate. Names arising in this way, for example, are fructose, maltose, lactose, xylose, and cellulose. These short, well-established names are still commonly used. They furnish no information on the chemical structures however, so a definitive carbohydrate nomenclature has been developed. From the definitive names, structural formulas can be written. Some of the terms involved in the definitive nomenclature are explained in the following paragraphs.
The simple sugars (monosaccharides0 are basically aliphatic polyhydroxy aldehydes and ketones: HOCH2- (CHOH) n-CHO and HOCH2- (CHOOH) n-1-C-O-Ch2OH, called “aldoses” and “ketoses,” respectively. However, it must be understood that cyclic hemiacetals of those open-chain forms prevail I solids and at equilibrium in solutions. In the definitive nomenclature, the suffix “ose” is appended to prefixes denoting the number of carbon atoms in the nomosaccaride; e.g. trioses (n=1), tetroses (n=2), pentoses (n=3), hexoses (n=4) to distinguish aldoses from ketoses, ketoses are designated as”-uloses.
” Thus, the simplest ketose, HOCH2-C:O-CH2OH, is a triulose; the most common ketose, D-fructose (levulose), is a hexlose. To designate the configurations of hydroxyl groups on the asymmetric carbon atoms of monosaccharides, the prefixes D and L are used together with prefixes derived from the trivial sugar names (e.g., D-glycero-, L-arabino-, D-xylo-) followed by pentose, hexose hexulose, etc.
As open-chain hydroxy aldehydes and hydroxyl ketenes, the monosaccharides are very reactive. They readly enolize in alkaline soluions to reduce ions such as Cu2+ and Fe(CN)63-. Therefore, they are called “reducing sugars”. Plants protect the reactive monosaccharides for transport and storage by condensing them with loss of water, into less reactive sugars, e.g., D-glucose and D-fructose, are condensing in such a way that their reactive functions are lost to form the
disaccharide no reducing sugar, sucrose. The less reactive sucrose is then transported to all parts of the plant for enzymin syntheses of oligo-and polysaccharides. From thousands or more D-glucose moieties of sucrose the glucans, starch and cellulose, are built. From the D-fructose moiety of sucrose, fructans such as inulin are assembled. Other polysaccharides are formed from other sugar, which rose by enzymic transformations of phosphorylated hexoes and sugar nucleotides.
The prefix “glyc,” is used in a generic sense to designate sugars and their derivatives; e.g., glycoses, g
lycosides, glycosans, glyconic glyceric, and glycuronic acids. The generic name for polysaccharides is “glycan”homoglycansare composed of single monosaccharide; for example, the D-glucans, cellulose and starch, release only D-glucose by hydrolysis. Other homoglycans (e.g., the hexcsans, D-galactan and D-manan, and the pentosans, L-arabinan and D-xy-lan) are uncommon in nature. Heteroglycans, composed of two or more different monosaccharides, are widely distributed than the homoglycans that are not glucans. Galactomnnans, glucomammans, arabinogalactans, and arabinoxylans are common diheteroglycans(composed of two sugars).the glycant vail over free glycoses in natural foods.
The reducing sugars are readily oxidized. mild oxidation of aldoses yields aldonic acids, HOCH2-(CHOH)n-COOH; e.g., gluconic acid(n=4).oxidation of both ends of the aldose molecule yields aldaric acids, HOOC-(CHOH)n-COOH; e.g., tartaric acid(n=2). Oxidation of the terminal CH2OH group of hexoses without oxidation of the reducing function (protected) produces hexuronic acids, HOOC-(CHOH)-CHO. The hexuronic acids are common monosaccharide constituents of many heteroglycans .for example, they are found in acidic hemicelluloses, pectic substances, alginpl and exudate gumes, and the mucopolysaccharides of mammalian tissues. Penturonic acids have not been found in nature.
Reduction of aldoses or ketoses yield sugar alcohols ,properly called …alditols,” HOCH2-(CHOH)n-CH2OH.the suffix “-itol “ is applied to the trivial prefixes to denote different alditols; e.g., D-glucitol, D-m
anniitol, xylitol. The triitol, gllyceritol (by common usage, glycerol, n=1), is the alditol moiety of fats.Glycerol and D-glucitol(sorbitol) are acceptable and useful food addiaffinity for water. Pentitols(n=3) and hexutols(n=4) are found in small amount in many fruits, vegetables and hexitol, perseitol (n=5), and an octitol have been isolated from avocados. Some aditols are nutritionally available; others are not.
Other types of carbohydrates found in food are the condensed N-acetylated amino sugars of mucopolysaccharides, glycoproteins, and chitin; the condense deoxy sugars of gum, mucilages, and nucleotides; glcosides (sugars condensed with nonsugars); glucosinolates (toxic thioglycosides); cyclitols (myoinositol, phytic acid); and reductone, L-ascorbic acid.
Complex carbohydrates, such as cellulose and hemicellulose, are largely indigestible, as are a number of origins
Carbohydrate Composition of Foods
Detains need more exact information on the carbohydrate compassion of foods. Food pressers
also make practical use of carbohydrate composition data. For example, the reducing sugar content of
fruits and vegetables that are to be dehydrated or processed with heat is frequently an indicator of the extent of nonenzymic browing that can expected during processing and storage. The possible hydrolysis of sucrose to reducing sugars during processing also is to be considered .the natural changes in carbohydrate composition that occur during maturation and post harvest ripening of plant foods is therefore of particular interest to food chemists.
Citrus fruits, which normally ripen on the tree and contain no starch, undergo little change in carbohydrate composition following harvest. However, in fruit that are picked before complete ripening (e.g., apples, bananas, pears), much of the stored starch is converted to sugars as ripening process. The reducing sugar content of potatoes also increase during the sun drying of grapes and dates, sucrose is converted to D-glucose and D-fructose; accordingly, the color of the dried products is deepened by nonenzymic browning reactions.
Green peas, green beans, and sweet corn are picked before maturity to obtain succulent textures and sweetness. Later the sugars would be converted to polysaccharides, water would be lost, and tough textures would develop. In soybean, which is allowed to mature completely before harvest, the starch reserve is depleted as sucrose and galactosy lsucroses (raffinose, stachyose, verbascose, etc.) are form in the malting of cereal grains, rapid conversions of reserve carbohydrate to sugars occur as enzy
reactive翻译mes are strongly activated.
In foods of animal origin, postmortem activity of enzymes must be considered when carbohydrate composition data is obtained. The glycogen of animal tissues, especially liver is rapidly depolymerized to D-glucose after slaughter, and immediate deep freezing is required to preserve the glycogen. Mammalian internal organs, such as liver, kidney, and brains also eggs and shellfish, provide small amount of D-glucose in the diet .Red fresh meats contain only traces of available carbohydrate (D-glucose, D-fructose, and D-ribose) and these are extracted into bouillons and broths. Dairy products provide the main source of mammalian carbohydrate. Whole cow‟s milk contain s about 4.9% carbohydrates and dried skim milk contains over 50% lactose.
Examination of food composition tables shows that in general, cereals are highest in starch content and lowest in sugars. Fruit are highest in free sugars and lowest in starch .on a dry basis, the edible portions of fruit usually contain 80-90% carbohydrate. Legumes occupy intermediate portion with regard to starch and are high in unavailable carbohydrate.
Glycosides of many types are widely distributed in plants. Certain biologically active thioglucosides, properly called “glucosinolates”, are found in significant amount in crucifers. Mustard oils, nitriles, and
goitrins are released by enzymic hydrolysis. Their suspected goitrogenic in humans have been investigated, but the amount of glucosnolates normally consumed in food such as fresh cabbage (300-1000ppm), cauliflower, Brussels sprouts, turning, rutabagas, and radishes are not now believed to cause adverse physiological effects. Cyan genetic glycosides, which release hydrogen cyanide by enzymic hydrolysis under certain condition of vegetable maceration, are known to be sources of acute toxicity in certain animal feeds; however they are not active in the customary foods of developed countries. Certain foreign varieties of lima beans
and manic root (cassava) may yield up to 0.3% hydrogen cyanide by weight, but lima beans distributed in the United States yield less than 0.02%. Saponins, the surface-active glycosides of steroids and triterpenoids, are found in low concentrations in tealeaves, spinach, asparagus, beets sugar beet (0.3%), yams, soybeans (0.5%), alfalfa (2-3%), and peanuts and other legumes.
食品科学家对碳水化合物有着多方面的兴趣。他们关心碳水化合物在各种食品中的含量，关心它的可利用性（营养上和经济上），它的提取方法和分析方法，它的商品形式和纯度，它的营养价值、生理效用以及在食品中的功能特性。要了解碳水化合物在加工食品中的功能特性，不仅要有单离态碳水化合物的物理、化学性质的知识，还要有碳水化合物与其它食物成分之间在加工食品中就地所发生的反应和相互作用的知识，以及这些反映变化对食品质量和食品可接受性的影响的知识。显然要了解这些知识是不容
易的。由于食品加工过程既影响食品的营养价值，也影响它的美学价值。所以了解碳水化合物在研磨、热处理、脱水、冷冻和贮藏过程中所经受的变化就显得特别重要。
建议学员们学习基础化学，这时认识碳水化合物有用性质的基础。了解和认识极性分子通过氢键、离子效应、取代基效应、与无机离子螯合、与脂类和蛋白质络和以及分解反应等的缔和作用将具有重要的意义。这些基础知识将有助于我们了解影响加工食品的质构和可接受性的性质（例如溶解度、吸湿性、扩散性、渗透性、粘度、可塑性、风味形成），了解使优质糕点、凝胶食品、糖衣、糖果和可复原脱水食品、冷冻食品得以形成的性质。
食品科学家实际工作目标之一是能够预测在把各种各样碳水化合物掺到加工食品中之后，可能会发生什么样的功能性质变化。作这样的预测要有丰富的用试探法摸索的经验，或者要具备有关结构的碳水化合物的性质的深奥知识，也可能上述两者都要具备。不过，科学的因果关系知识只有在它缩短了工业产品试制周期之时才受到高度的重视。
碳水化合物的来源、种类和技术名称
外行人的碳水化合物概念一般仅包括食物中能产生热量和脂肪的糖和淀粉，而食品科学家还知道许多摄入的他种碳水化合物。
由于大多数人喜欢糖的甜味和熟淀粉的口感，所以它们由于经常打交道而对食糖、（蔗糖）、转化糖（蔗糖水解产物）、淀粉糖浆（D-葡萄糖和麦芽糖）、乳糖和含淀粉多的食品十分熟悉。这些碳水化合物都有很好的营养价值，即它们可分为人体所消化（水解成单糖成分）和利用。相反，食用纤维类碳水化合物（纤维素、半纤维素、戊聚糖、果胶物质）因其大部分不能为人体所利用而往往被忽视。食用纤维类碳水化合物不能有效的被消化酶水解；尽管这样，他对人体的健康可能相当重要。
天然食物和加工食物中的碳水化合物被分成人体可利用和不可利用的两类。可利用的碳水化合物在吸收、利用的程度上也有差别，要看他的摄入量、伴随食物的种类以及人体在消化酶互补情况上和肠道输送机制上的差异而定。大家都知道，除了糊化淀粉大致上没有问题以外，所有可利用碳水化合物都有吸收不良的问题和有害的生理影响。
重要的是要意识到，在反刍动物方面，数量最丰富的人类不可利用的多糖类纤维素受到了部分水解，变成了淀粉消化时所形成的高度可利用糖，即D-葡萄糖。食草动物利用它们

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