SEALED MAINTENANCE FREE BATTERY
MATERIAL SAFETY DATA SHEET
SECTION1-CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer’s name：CAMEL GROUP BATTERY TRADING CO.,LTD
Adress:NO.4ZHUIRI ROAD,HI-TECH INDUSTRIAL DEVELOPMENT AREA,XIANGFAN,HUBEI,CHINA post code:441003Tel：+867103344102Fax：+867103343035
SECTION2-COMPOSITION/INFORMATION ON INGREDIENTS main technical specification for Low-maintenance Batteries(Without Acid)：
Battery type Rating valve
V Rating capacity
Ah
Net weight
KG
CCA
A
Dimension(MAX)
L*W*H*TH（mm）
58827128822640352*175*190*190
C.A.S.
7439-92-1 7440-36-0 7440-38-2 7664-93-9 7440-70-2 7440-31-5PRINCIPALHAZARDOUSCOMPONEN
T(S)(chemical&common name(s)
Lead/Lead Oxide/Lead Sulfate
Antimony
Arsenic
Sulfuric Acid(Battery Electrolyte)
Calcium
Tin
Hazard Category
Acute-Chronic
Chronic
Acute-Chronic
Reactive-Oxidizer Acute-Chronic
Reactive
Chronic
%
55-70%
0-5%
<1%
20-35%
<0.15%
<0.3%
ACGIH TLV
0.05mg/m3
0.5mg/m3
0.01mg/m3
1.0mg/m3
Not established
2.0mg/m3
OSHA
PEL-TWA
0.05mg/m3
0.5mg/m3
0.01mg/m3
1.0mg/m3
reactive to
Not established
2.0mg/m3
NOTE:PEL's for individual states may differ from OSHA PEL's.Check with local authorities for the applicable state PEL's.
OSHA-Occupational Safety and Health Administration;ACGIH-American Conference of Governmental Industrial Hygienists;NIOSH-National Institute for Occupational Safety and Health.
COMMON NAME:(Used on label)Maintenance-free Batteries
(Trade Name&Synonyms)Lead-Acid Storage Battery,With Acid;Low-maintenance Batteries With Acid
Chemical Family:Toxic and Corrosive Material Mixture
Chemical Name:Lead-Acid Storage Battery Formula:Lead and Acid(electrolyte)
Declare:Maintenance Batteries,With Acid(Electrolyte)and doesnot Hg;
NOTE:before using,immit Battery Sulfuric Acid(Battery Electrolyte)Density must equal to1.28(25℃)
SECTION3-
HAZARD
IDENTIFICATION
Components
Density Melting Point Solubility(in H2O)Odor Appearance
Lead11.34327.4°C None None Silver-Gray Metal
Lead Sulfate  6.21170°C40mg/l(15°C)None White Powder
Lead Dioxide9.4290°C None None Brown Powder
Fiberglass Separator N/A N/A Slight Toxic White Fibrous Glass Membrane Container(ABS or PP)N/A N/
A NONE No Odor Solid Plastics
SECTION4-FIRST AID MEASURES
Emergency and First Aid
Procedures
Contact with internal components if battery is opened/broken.
1.Inhalation Remove to fresh air and provide medical oxygen/CPR if needed.Obtain medical attention.
2.Eyes Immediately flush with water for at least15minutes,hold eyelids open.Obtain medical attention.
3.Skin Flush contacted area with large amounts of water for at least15minutes.Remove contaminated
clothing and obtain medical attention if necessary.
4.Ingestion Do not induce vomiting.If conscious drink large amounts of water/milk.Obtain medical attention.
Never give anything by mouth to an unconscious person.
SECTION5-FIREFIGHTING MEASURES
Components Flash
Point Explosive
Limits
Comments
Lead None None
Hydrogen259℃4%-74.2%Emit hydrogen only if over charged(Voltage>2.4VPC).To avoid the chance of a fire
or explosion,keep sparks and other sources of ignition away from the battery.
Extinguishing Media:Dry chemical,Foam,CO2
Fiberglass
Separator
N/A N/A Toxic vapors may be released.In case of fire:wear self-contained breathing apparatus. ABS None N/A Danger:Vapors may cause Flash Fire.Harmful or Fatal if Swallowed.Vapor Harmful.
PP None N/A Temperatures over300°C(572°F)may release combustible gases.In case of fire:
wear positive pressure self-contained breathing apparatus.
Flash Point Not Applicable Flammable Limits in Air%by Volume(When charging)
Hydrogen(H2)Lower4.1%Upper74.2%
Extinguisher Media Class ABC,
CO2,Halon
Auto-Ignition Temperature
Polypropylene675o F
Special Fire Lead-acid batteries do not burn or burn with difficulty.Do not use water on fires where molten metal is present.Extinguish fire with agent
Fighting suitable for surrounding combustible materials.Cool exterior of battery if exposed to fire to prevent rupture.The acid mist and vapors
Procedures generated by heat or fire are corrosive.Use NIOSH approved self-contained breathing apparatus(SCBA)and full protective equipment
operated in positive-pressure mode.
Unusual Fire and Hydrogen gas and sulfuric acid vapors are generated upon overcharge and polypropylene case failure.Ventilate charging areas as per
Explosion Hazards ACGIH Industrial Ventilation:A Manual of Recommended Practice and National Fire Code,1980Vol.1,P.12,B-9,10.Hydrogen gas may be flammable or explosive when mixed with air,oxygen,and chlorine.Avoid open flames/sparks/other sources of ignition near battery.To avoid
risk of fire or explosion,keep sparks or other sources of ignition away from batteries and do not allow metallic materials to simultaneously contact negative and positive terminals of cells and batteries.SULFURIC ACID REACTS VIOLENTLY WITH WATER/ORGANICS.
SECTION6-ACCIDENTAL RELEASE MEASURES
Procedures for Cleanup:Stop release,if possible.Avoid contact with any spilled material.Contain spill,isolate hazard area,and deny entry.Limit site access to emergency responders.Neutralize with sodium bicarbonate,soda ash,lime or other neutralizing agent.Place battery
in suitable container for disposal.Dispose of contaminated material in accordance with applicable local,state and federal regulations.Sodium bicarbonate,soda ash,sand,lime or other neutralizing agent should be kept on-site for spill remediation.
Personal Precautions:Acid resistant aprons,boots and protective clothing.ANSI approved safety glasses with side shields/face shield recommended.Ventilate enclosed areas.
Environmental Precautions:Lead and its compounds and sulfuric acid can pose a severe threat to the environment.Contamination of water, soil,and air should be prevented.
SECTION7-HANDLING AND STORAGE
Precautions to be Taken in Handling and Storage Keep away from flames during and immediately after charging.Combustion or overcharging may create or liberate toxic and hazardous gases and liquids including hydrogen,sulfuric acid mist,sulfur dioxide,sulfur trioxide,stibine,arsine and sulfuric acid.Store batteries in cool,dry,well-ventilated area.Do not short circuit battery terminals,or remove vent caps during storage or recharging.Protect battery from physical damage.
Other Precautions GOOD PERSONAL HYGIENE AND WORK PRACTICES ARE MANDATORY.Refrain from eating,drinking or smoking in work areas.Thoroughly wash hands,face,neck,and arms before eating,drinking or smoking.Launder soiled clothing before reuse. Emptied batteries contain hazardous sulfuric acid residue.
SECTION8-EXPOSURE CONTROLS AND PERSONAL PROTECTION
Respiratory Protection (Specify Type)Acid gas NIOSH approved respirator is required when the PEL is exceeded or employee experiences respiratory irritation. When exposure levels are unknown or when firefighting,wear a self-contained breathing apparatus with a full facepiece operated in positive pressure mode
Ventilation Must be provided when charging
in an enclosed area.Change air
every15min.
Local
Exhaust
When PEL is
exceeded.
Mechanical
(General)
Normal mechanical ventilation
recommended for stationary
applications.
Protective Gloves Wear rubber or plastic acid resistant gloves with
elbow length gauntlet when filling batteries.
Eye
Protection
ANSI approved safety glasses with side shields/face shield
recommended.Safety goggles.
Other Protective Clothing or Equipment Ventilation as described in the Industrial Ventilation Manual pr
oduced by the American Conference of Governmental Industrial Hygienists,shall be provided in areas where exposures are above the PEL or TLV specified by OSHA or other local,state and federal regulations.Acid-resistant rubber or plastic apron,boots and protective clothing.Safety shower and eyewash.
SECTION9-PHYSICAL AND CHEMICAL PROPERTIES
Percent Volatile by Volume(%) Without Acid
Solubility in Water Appearance and Odor Melting Point Polypropylene>320o F
x Vapor Density Hydrogen(Air=1):0.069At STP
Evaporation Rate Not Applicable
Battery:Polypropylene or hard rubber case,solid;
may be contained within an outer casing of aluminum or steel.Case has metal terminals. Lead(internal):Gray,metallic,solid;Brown/grey oxide
SECTION10-STABILITY AND REACTIVITY
Stability Unstable Stable Conditions
to Avoid High temperatures-cases decompose at>320°F.Avoid overcharging and smoking,or sparks near battery surface and rapid overcharge.
Incompatibility(Materials to Avoid)Sparks,Open flames,Keep battery case away from strong oxidizers.
Hazardous Decomposition Products An explosive hydrogen/oxygen mixture within the battery may occur during charging.Combustion can produce
carbon dioxide(CO2)and carbon monoxide(CO).Molten metals produce fumes and/or vapor that may be
toxic or respiratory irritants.
Hazardous Polymerization
May Occur
Will Not Occur Do not overcharge SECTION11-TOXICOLOGICAL INFORMATION
GENERAL:The primary routes of exposure to lead are ingestion or inhalation of dust and fumes.
ACUTE:
INGESTION/INHALATION:Exposure to lead and its compounds may cause headache,nausea,vomiting,abdominal spasms, fatigue,sleep
disturbances,weight loss,anemia,and pain in the legs,arms and joints.Kidney damage,as well as anemia,can occur from acute exposure.
CHRONIC:
INHALATION/INGESTION:Prolonged exposure to lead and its compounds may produce many of the symptoms of short-term exposure and may also
cause central nervous system damage,gastrointestinal disturbances,anemia,and wrist drop.Symptoms
of central nervous system damage include
fatigue,headaches,tremors,hypertension,hallucinations,convulsions and delirium.Kidney dysfunction and possible injury has also been associated
with chronic lead poisoning.Chronic over-exposure to lead has been implicated as a causative agent for the impairment of male and female
reproductive capacity,but there is,at present,no substantiation of the implication.Pregnant women should be protected from excessive exposure.
Lead can cross the placental barrier and unborn children may suffer neurological damage or developmental problems due to excessive lead exposure in
pregnant women.
SECTION12-ECOLOGICAL INFORMATION
In most surface water and groundwater,lead forms compounds with anions such as hydroxides,carbonates,sulfates, and phosphates and precipitates out of the water column.Lead may o
ccur as sorbed ions or surface coatings on sediment mineral particles or may be carried in colloidal particles in surface water.Most lead is strongly retained in soil,resulting in little mobility.Lead may be immobilized by ion exchange with hydrous oxides or clays or by chelation with humic or fulvic acids in the soil.Lead(when in the dissolved phase)is bioaccumulated by plants and animals, both aquatic and terrestrial.
SECTION13-DISPOSAL CONSIDERATIONS
Waste Disposal Lead-acid batteries are completely recyclable.Return whole scrap batteries to distributor,manufacturer or lead smelter for recycling.Methods For information on returning batteries to Concorde for recycling call+860710 7617594.For neutralized spills,place residue in acid-resistant containers with sorbent material,sand or earth and dispose of in accordance with local,state and federal regulations for acid and lead compounds.Contact local and/or state environmental officials regarding disposal information.
SECTION14-TRANSPORT INFORMATION
UN DOT PROPER SHIPPING NAME:Batteries,wet,non-spillable electric storage CNA.DOT HAZARD CLASS:8
U.S.DOT ID NUMBER:UN2794
U.S.DOT PACKING GROUP:III

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