Designation:B863–10
Standard Specification for
Titanium and Titanium Alloy Wire 1
This standard is issued under the fixed designation B863;the number immediately following the designation indicates the year of original adoption or,in the case of revision,the year of last revision.A number in parentheses indicates the year of last reapproval.A superscript epsilon (´)indicates an editorial change since the last revision or reapproval.
1.Scope*
1.1This specification covers titanium and titanium alloy wire as follows:
1.1.1Grade 1—Unalloyed titanium,low oxygen,1.1.2Grade 2—Unalloyed titanium,standard oxygen,
1.1.
2.1Grade 2H —Unalloyed titanium (Grade 2with 58ksi minimum UTS),
1.1.3Grade 3—Unalloyed titanium,medium oxygen,1.1.4Grade 4—Unalloyed titanium,high oxygen,
1.1.5Grade 5—Titanium alloy (6%aluminum,4%vana-dium),
1.1.6Grade 6—Titanium alloy (5%aluminum,
2.5%tin),1.1.7Grade 7—Unalloyed titanium plus 0.12to 0.25%palladium,standard oxygen,
1.1.7.1Grade 7H —Unalloyed titanium plus 0.12to 0.25%palladium (Grade 7with 58ksi minimum UTS),
1.1.8Grade 9—Titanium alloy (3%aluminum,
2.5%va-nadium),
1.1.9Grade 11—Unalloyed titanium plus 0.12to 0.25%palladium,low oxygen,
1.1.10Grade 12—Titanium alloy (0.3%molybdenum,0.8%nickel),
1.1.11Grade 13—Titanium alloy (0.5%nickel,0.05%ruthenium),
1.1.12Grade 14—Titanium alloy (0.5%nickel,0.05%ruthenium),
1.1.13Grade 15—Titanium alloy (0.5%nickel,0.05%ruthenium),
1.1.14Grade 16—Unalloyed titanium plus 0.04to 0.08%palladium,standard oxygen,
1.1.14.1Grade 16H —Unalloyed titanium plus 0.04to 0.08%palladium (Grade 16with 58ksi minimum UTS),1.1.15Grade 17—Unalloyed titanium plus 0.04to 0.08%palladium,low oxygen,
1.1.16Grade 18—Titanium alloy (3%aluminum,
2.5%vanadium)plus 0.04to 0.08%palladium,
1.1.17Grade 19—Titanium alloy (3%aluminum,8%vanadium,6%chromium,4%zirconium,4%molybdenum),1.1.18Grade 20—Titanium all
oy (3%aluminum,8%vanadium,6%chromium,4%zirconium,4%molybdenum)plus 0.04to 0.08%palladium,
1.1.19Grade 21—Titanium alloy (15%molybdenum,3%aluminum,
2.7%niobium,0.25%silicon),
1.1.20Grade 23—Titanium alloy (6%aluminum,4%vanadium with extra low interstitial elements,ELI),
1.1.21Grade 24—Titanium alloy (6%aluminum,4%vanadium)plus 0.04%to 0.08%palladium,
1.1.22Grade 25—Titanium alloy (6%aluminum,4%vanadium)plus 0.3to 0.8%nickel and 0.04to 0.08%palladium,
1.1.23Grade 26—Unalloyed titanium plus 0.08to 0.14%ruthenium,
1.1.23.1Grade 26H —Unalloyed titanium plus 0.08to 0.14%ruthenium (Grade 26with 58ksi minimum UTS),1.1.24Grade 27—Unalloyed titanium plus 0.08to 0.14%ruthenium,
1.1.25Grade 28—Titanium alloy (3%aluminum,
2.5%vanadium)plus 0.08to 0.14%ruthenium,
1.1.26Grade 29—Titanium alloy (6%aluminum,4%vanadium with extra low interstitial elements,ELI)plus 0.08to 0.14%ruthenium,
1.1.27Grade 32—Titanium alloy (5%aluminum,1%tin,1%vanadium,1%zirconium,0.8%molybdenum),
1.1.28Grade 33—Titanium alloy (0.4%nickel,0.015%palladium,0.025%ruthenium,0.15%chromium),
1.1.29Grade 34—Titanium alloy (0.4%nickel,0.015%palladium,0.025%ruthenium,0.15%chromium),
1.1.30Grade 35—Titanium alloy (4.5%aluminum,2%molybdenum,1.6%vanadium,0.5%iron,0.3%silicon),1.1.31Grade 36—Titanium alloy (45%niobium),
1.1.32Grade 37—Titanium alloy (1.5%aluminum),and 1.1.33Grade 38—Titanium alloy (4%aluminum,
2.5%vanadium,1.5%iron).
N OTE 1—H grade material is identical to the corresponding numeric grade (that is,Grade 2H =Grade 2)except for the higher guaranteed
1
This specification is under the jurisdiction of ASTM Committee B10on Reactive and Refractory Metals and Alloys and is the direct responsibility of Subcommittee B10.01on Titanium.
Current edition approved May 1,2010.Published May 2010.Originally approved in 1995.Last previous edition approved in 2009as B863–09.DOI:10.1520/B0863-10.
1
*A Summary of Changes section appears at the end of this standard.
Copyright.(C)ASTM International,100Barr Harbour Dr.,P.O.box C-700West Conshohocken,Pennsylvania 19428-2959,United States
minimum UTS,and may always be certified as meeting the requirements of its corresponding numeric grade.Grades 2H,7H,16H,and 26H are intended primarily for pressure vessel use.
The H grades were added in response to a user association request based on its study of over 5200commercial Grade 2,7,16,and 26test reports,where over 99%met the 58minimum UTS.
1.2The values stated in inch-pound units are to be regarded as standard.The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
2.Referenced Documents 2.1ASTM Standards:2
E8Test Methods for Tension Testing of Metallic Materials E29Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E539Test Method for X-Ray Fluorescence Spectrometric Analysis of 6Al-4V Titanium Alloy
E1409Test Method for Determination of Oxygen and Nitrogen in Titanium and Titanium Alloys by the Inert Gas Fusion Technique
E1447Test Method for Determination of Hydrogen in Titanium and Titanium Alloys by Inert Gas Fusion Ther-mal Conductivity/Infrared Detection Method
E1941Test Method for Determination of Carbon in Refrac-tory and Reactive Metals and Their Alloys
E2371Test Method for Analysis of Titanium and Titanium Alloys by Atomic Emission Plasma Spectrometry
E2626Guide for Spectrometric Analysis of Reactive and Refractory Metals 2.2AWS Standard:3
AWS A5.16/A5.16M-2007Specification for Titanium and Titanium Alloy Welding Electrodes and Rods 3.Terminology
3.1Definitions of Terms Specific to This Standard:
3.1.1coils ,n —wire in coil form with pitch and cast as described by purchaser.
3.1.2straight lengths ,n —wire in straight lengths,generally made by straightening wire from coils by the producer.3.1.3weld wire ,n —round wire for welding.
3.1.4wire ,n —rounds,flats,or special shapes from 0.020in.(0.5mm)to 0.250in.(6.4mm)in thickness or major dimension.
4.Product Classification 4.1Wire —See 3.1.4.
4.2Coils —Coiled wire may be spooled on spools if re-quired by the user.
4.3Straight Lengths —After straightening,it may be neces-sary to perform cleaning or other finishing operations.Straight
lengths are normally 10to 12ft long (random).Exact lengths may be specified by the purchaser when necessary.
4.4Filler Metal or Weld Wire —Wire for welding filler metal application has special requirements for more restrictive chemistry that allows for oxygen increase inherent in most welding processes used for titanium,and has tighter limits on iron,carbon,nitrogen,and hydrogen.AWS ER Ti-XX grades are specifically designed for welding the corresponding ASTM XX wrought or cast material grades.In addition,special requirements for spooling,such as layer winding,cast,and helix,packaging to maintain cleanliness,and identification are necessary.Use AWS A
5.16/A5.16M-2007for wire for titanium and titanium alloy filler metal.5.Ordering Information
5.1.Orders for material under this specification shall include the following information as applicable:5.1.1Grade number (Section 1),
5.1.2Product description (Sections 3and 4),5.1.3Chemistry (Table 1),
5.1.4Mechanical properties (if applicable,Table 2),5.1.5Marking and packaging (Section 17),5.1.6Finish (Section 9),
5.1.7Applicable dimensions including size,thickness,width,spool size,coil diameter,and length (exact,random,multiples)or print number,
5.1.8Required reports (Section 16),5.1.9Special tests or requirements,and
5.1.10Disposition of rejected material (Section 15).
6.Chemical Composition
6.1The grades of titanium and titanium alloy metal covered by this specification shall conform to the requirements as to chemical composition prescribed in Table 1.
6.1.1The elements listed in Table 1are intentional alloy additions or elements which are inherent to the manufacture of titanium sponge,ingot or mill product.
6.1.1.1Elements other than those listed in Table 1are deemed to be capable of occurring in the grades listed in Table 1by and only by way of unregulated or unanalyzed scrap additions to the ingot melt.Therefore,product analysis for elements not listed in Table 1shall not be required unless specified and shall be considered to be in excess of the intent of this specification.
6.1.2Elements intentionally added to the melt must be identified,analyzed and reported in the chemical analysis.6.2When agreed upon by the producer and purchaser and requested by the purchaser in his written purchase order,chemical analysis shall be completed for specific residual elements not listed in this specification.
6.3Product Analysis —Product analysis tolerances do not broaden the specified heat analysis requirements,but cover variations between laboratories in the measurement of chemi-cal content.The manufacturer shall not ship material which is outside the limits specified in Table 1for the applicable grade.Product analysis limits shall be as specified in Table 3.
2
For referenced ASTM standards,visit the ASTM website,,or contact ASTM Customer Service at For Annual Book of ASTM Standards volume information,refer to the standard’s Document Summary page on the ASTM website.3
Available from American Welding Society (AWS),550NW LeJeune Rd.,Miami,FL 33126,
B863–10
2
7.Mechanical Requirements
7.1Annealed material supplied under this specification shall conform to the mechanical property requirements given in Table2,as applicable.Material may be ordered in the cold worked condition to higher ultimate tensile strengths and lower elongation levels as agreed upon between the supplier and the purchaser.
7.2Tension testing shall be performed in accordance with Test Methods E8.Tensile properties shall be determined using a strain rate of0.003to0.007in./in./min.(SI equivalent mm/mm/min)through the yield strength,and then the cross-head speed shall be increased so as to produce fracture in approximately one additional minute.
7.2.1Wire and shapes with the diameter or smallest dimen-sion between0.250and0.125in.(6.4to3.2mm)shall have the yield strength determined in accordance with Test Methods E8, and the elongation measured and reported over4D(4diam-eters).
7.2.2Wire and shapes with the diameter or smallest dimen-sion less than0.125in.(3.2mm)shall have the elongation determined over2in.(50.8mm)unless defined otherwise by the purchaser.The reported value shall be expressed as a percentage equivalent.
7.3The yield strength requirements in Table2only apply to sizes of0.125in.(3.2mm)and above.
8.Dimensions,Weight,and Permissible Variations
8.1Size—Tolerances on diameter of titanium and titanium alloy material covered by this specification shall be as specified in Table4.
TABLE2Tensile Requirements
Tensile Strength Yield Strength
(0.2%Offset)
Elongation A
Grade
minimum minimum
min,% ksi MPa ksi MPa
135(240)20(138)20
250(345)40(275)18
2H B,C58(400)40(275)18
365†(450)†55(380)18
480†(550)†70(483)15 5130(895)120(828)10 6120(828)115(793)10
750(345)40(275)18
7H B,C58(400)40(275)18
990(620)70(483)15 1135(240)20(138)20 1270(483)50(345)18 1340(275)25(170)18 1450(410)40(275)20 1570(483)50(345)15 1650(345)40(275)20
16H B,C58(400)40(275)18 1735(240)20(138)20 1890(620)70(483)10
19D,E115(793)110(759)10
20D,E115(793)110(759)10
21D,E115(793)110(759)10 23115(793)110(759)10 24130(895)120(828)10 25130(895)120(828)10 2650(345)40(275)20
26H B,C58(400)40(275)18 2735(240)20(138)24 2890(620)70(483)15 29120(828)110(759)10 321006898558610 3350(345)40(275)20 3465(450)55(380)18 35130(895)120(828)5 3665(450)60(410)10 3750(345)31(215)18 38130(895)115(794)10
A Elongation shall be measured as described in7.2.1and7.2.2.
B Material is identical to the corresponding numeric grade(that is,Grade2H= Grade2)except for th higher guaranteed minimum UTS,and may be dual certified with its corresponding numeric grade.Grade2H,7H,16H,and26H are intended primarily for pressure vessel use.
C The H grades were added in response to a user association request based on its study of over5200commercial Grade2,7,16,and26test reports,where over 99%met the58ksi minimum UTS.
D Properties for material in the solution treated condition.
E Material is normally purchased in the solution treated condition.Therefore, properties for aged material shall be negotiated between manufacturer and purchaser.
†Tensile strength for Grade3and Grade4was corrected editorially.
TABLE3Permissible Variations in Product Analysis Element
Product Analysis Limits,
max or range,%
Permissible Variation in
Product Analysis Aluminum0.5to2.560.20
Aluminum 2.5to6.7560.40
Carbon0.10+0.02
Chromium0.1to0.260.02
Chromium 5.5to6.560.30
Hydrogen0.02+0.002
Iron0.80+0.15
Iron 1.2to1.860.20
Molybdenum0.2to0.460.03
Molybdenum0.6to1.260.15
Molybdenum 1.5to4.560.20
Molybdenum14.0to16.060.50
Nickel0.3to0.960.05
Niobium 2.2to3.260.15
Niobium>3060.50
Nitrogen0.05+0.02
Oxygen0.30+0.03
Oxygen0.31to0.4060.04
Palladium0.01to0.0260.002
Palladium0.04to0.0860.005
Palladium0.12to0.2560.02
Ruthenium0.02to0.0460.005
Ruthenium0.04to0.0660.005
Ruthenium0.08to0.1460.01
Silicon0.06to0.4060.02
Tin0.6to3.060.15
Vanadium0.6to4.560.15
Vanadium7.5to8.560.40
Zirconium0.6to1.460.15
Zirconium 3.5to4.560.20
Residuals A(each)0.15+0.02
A A residual is an element in a metal or alloy in small quantities inherent to the manufacturing process but not added intentionally.
TABLE4Permissible Variations in Size for Titanium Wire
Specified Diameter,in.
(dimension if shape wire)
Variation,in.reactive metal
Wire as Coil
or on Spools
Cut Straight
Lengths A
0.020to0.045,incl60.00160.0015
over0.045to0.062,incl60.0015†60.002
over0.062to0.090,incl60.00260.0025
over0.090to0.187,incl60.00360.003
over0.187to0.25060.00460.004
A Length tolerance for cut lengths is60.25in.for lengths up to and including36 in.
†Editorially
corrected. 4
8.2Weight—The shipping weight of any item of an ordered size in anyfinish condition may exceed the theoretical weight by as much as10%.
9.Workmanship,Finish,and Appearance
9.1Titanium and titanium alloy wire shall be free of injurious external and internal imperfections of a nature that will interfere with the purpose for which the wire is intended. Material may be furnished as polished,chemically cleaned, ground,or mechanically descaled,and shall have a clean, contamination-free surface.
9.1.1For specific applications,afinal sizing draw pass may be specified,with lubricants to be applied(or allowed to remain)on the wire.
10.Chemical Analysis
10.1Samples for chemical analysis shall be representative of the material being tested.The utmost care must be used in sampling titanium for chemical analysis because of its great affinity for elements such as oxygen,nitrogen,and hydrogen. Therefore,in cutting samples for analysis,the operation should be carried out insofar as possible in a dust-free atmosphere. Chips should be collected from clean met
al and tools should be clean and sharp.Hydrogen analysis shall be performed on the final cleaned wire product.
11.Methods of Chemical Analysis
11.1The chemical analysis shall normally be conducted using the ASTM standard test methods referenced in2.1.Other industry standard methods may be used where the ASTM test methods in2.1do not adequately cover the elements in the material or by agreement between the producer and purchaser. Alternate techniques are discussed in Guide E2626.
12.Retests
12.1If the results of a chemical or mechanical property test lot are not in conformance with the requirements of this specification,the lot may be retested at the option of the manufacturer.The frequency of the retest will double the initial number of tests.If the results of the retest conform to the specification,then the retest values will become the test values for certification.Only original conforming test results or the conforming retest results shall be reported to the purchaser.If the results for the retest fail to conform to the specification,the material will be rejected in accordance with Section15.13.Referee Test and Analysis
13.1In the event of a disagreement between the manufac-turer and the purchaser on the conformance of the material to the requirements of this specification,a mutually acceptable referee shall perform the tests in question using the ASTM standard methods in2.1.The referee’s testing shall be used in determining conformance of the material to this specification.
14.Rounding-Off Procedure
14.1For purposes of determining conformance with the specifications contained herein,an observed or a calculated value shall be rounded off to the nearest unit in the last right-hand significant digit used in expressing the limiting value.This is in accordance with the round-off method of Practice E29.
15.Rejection
15.1Material not conforming to this specification or to authorized modifications shall be subject to rejection.Unless otherwise specified,rejected material may be returned to the manufacturer at the manufacturer’s expense,unless the pur-chaser receives,within three weeks of notice of rejection,other instructions for disposition.
16.Certification
16.1The manufacturer shall supply at least one copy of the report certifying that the material supplied has been manufac-tured,inspected,sampled,and tested in accordance with the requirements of this specification and that the results of chemical analysis,tensile and other tests meet the requirements of this specification for the grade specified.The report shall include results of all chemical analysis,tensile tests,and all other tests required by the specification.
17.Packaging and Package Marking
17.1Marking—Unless otherwise specified,individual packages of straight wires or coils of wire shall have attached an appropriate tag containing the purchase order number,the specification number,the alloy,the nominal size,and the manufacturer’s lot number,or the product shall be boxed and the box marked with the same information.
17.2Packaging—Unless otherwise specified,material pur-chased under this specification may be packaged for shipment by boxing or crating with adequate protection in accordance with the manufacturer’s standard practice.
18.Keywords
18.1titanium;titanium alloy;weld wire;
wire 5
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